Similarities and differences between metal cages and frame cages in terms of materials

Dec 18, 2025

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Although both MOCs and MOFs contain metal-organic coordination bonds, there are fundamental differences:

 

Dimensionality: MOCs are 0-dimensional discrete molecules, while MOFs are 2D or 3D infinitely extended networks.

 

Solubility: Most MOCs are soluble, while MOFs are generally insoluble.

 

Stability: MOFs generally have higher thermal stability.

 

Application focus: MOCs excel in molecular recognition, while MOFs are more suitable for gas storage.

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